106431-23-6

Basic information

• Product Name: [2-(1.3-dithian-2-ylidine)-1-phenylethyl]tri-n-butyltin
• CAS NO: 106431-23-6
• Molecular Weight: 511.424
• Mol File: 106431-23-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [2-(1.3-dithian-2-ylidine)-1-phenylethyl]tri-n-butyltin(CAS DataBase Reference)
• NIST Chemistry Reference: [2-(1.3-dithian-2-ylidine)-1-phenylethyl]tri-n-butyltin(106431-23-6)
• EPA Substance Registry System: [2-(1.3-dithian-2-ylidine)-1-phenylethyl]tri-n-butyltin(106431-23-6)

Safety Data

• Hazardous Substances Data: 106431-23-6(Hazardous Substances Data)

Upstream product

• 69178-10-5 2-styryl-1,3-dithiane 
• 1461-22-9 tributyltin chloride 

Relevant articles and documents

ORGANOTIN DERIVATIVES IN THE UMPOLUNG OF 1,3-DITHIAN-2-YLIDES TO 1,3-DITHIAN-2-YLIUM SALTS

Lithiated 1,3-dithianes react with trialkyltin or triphenyltin chlorides to form the corresponding 1,3-dithian-2-yltin compounds.The dithiane C(2)-Sn bond in the trialkyltin or triphenyltin compounds is selectively cleaved by iodine, with formation of 1,3-dithian-2-ylium triiodides which can be transformed into the corresponding tetrafluoroborate salts.The (1)H and (13)C NMR data are consistent with the salt like structures.The ambident nature of β-styryl derivatives is discussed.Preferential cleavage of the C(2)-Sn bond in the stannyl derivatives is evident in the mass spectra.