106455-87-2

Upstream product

• 13291-18-4 isopropenylmagnesium bromide 
• 93000-77-2 (1α,2β,4β,6α)-3,8-dioxatricyclo<4.2.1.0^2,4>nonan-7-one 
• 98903-43-6 exo-4-<(trimethylsilyl)oxy>-6-oxabicyclo<3.2.1>oct-2-en-7-one 

Downstream Products

• 98903-44-7 (1α,4β,5α)-<<5-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-α-(1-methylethenyl)-4-<(trimethylsilyl)oxy>-2-cyclohexen-1-yl>methoxy>trimethylsilane 
• 106455-91-8 (1α,5α,6β)-(1,1-dimethylethyl)dimethyl-<<5-<2-methyl-3-<(trimethylsilyl)oxy>-2-propenyl>-6-<(trimethylsilyl)oxy>-3-cyclohexen-1-yl>oxy>silane 
• 106455-89-4 (1α,4β,5α)-5<<(1,1-dimethylethyl)dimethylsilyl>oxy>-α-(1-methylethenyl)-4-<(trimethylsilyl)oxy>-2-cyclohexene-1-methanol 

Relevant academic research and scientific papers

An Approach to the Synthesis of Bactobolin and the Total Synthesis of N-Acetylactinobolamine: Some Remarkably Stable Hemiacetals

The key steps in the synthesis of N-acetylactinobolamine were the siloxy-Cope rearrangemnt 17 --> 18 and the transformation of pseudoglycal 54, via its glycosyl azide derivative 55, to hemiacetal 56.This hemiacetal, as well as closely related hemicaetals

A Total Synthesis of N-Acetylactinobolamine

Selective osmylation of a 3-azidoglycal in equilibrium with a 1-azidopseudoglycal is used to reach the title system.