106456-85-3

Upstream product

• 127732-82-5 4-(1,3-oxathiolan-2-yl)benzonitrile 
• 540-63-6 ethane-1,2-dithiol 
• 619-65-8 4-cyanobenzoic Acid 
• 105-07-7 4-cyanobenzaldehyde 

Downstream Products

• 7153-22-2 ethyl 4-cyanobenzoate 
• 105-07-7 4-cyanobenzaldehyde 
• 78784-21-1 4-[1,3]dithiolan-2-yl-benzaldehyde 

Relevant academic research and scientific papers

Thioacetalization of carbonyl compounds by zeolite HSZ-360 as a new, effective heterogeneous catalyst

Thioacetal can be efficiently obtained at room temperature by simply dissolving the appropriate carbonyl compounds and 1,2-ethanedithiol, in dichloromethane, with zeolite HSZ-360 as a new heterogeneous catalyst. Satisfactory to good yields are obtained ev

Crystallinity after decarboxylation of a metal-carboxylate framework: indestructible porosity for catalysis

We report a curious case study of a Zr(iv)-carboxylate framework, which retains significant crystalline order after cascade thermocyclization of its linker components, and - more notably - after the crucial carboxylate links were severed by heat. Vigorous heat treatment (e.g., 450 °C and above) benzannulates the multiple alkyne groups on the linker to generate linked nanographene blocks and to afford real stability. The resultant Zr oxide/nanographene hybrid solid is stable in saturated NaOH and concentrated H3PO4, allowing a convenient anchoring of H3PO4into its porous matrix to enable size-selective heterogeneous acid catalysis. The Zr oxide components can also be removed by strong hydrofluoric acid to further enhance the surface area (up to 650 m2g?1), without collapsing the nanographene scaffold. The crystallinity order and the extensive thermal transformations were characterized by X-ray diffraction, scanning transmission electron microscopy (STEM), IR, solid state NMR and other instrumental methods.

Iron(III) fluoride: A highly efficient and versatile catalyst for the protection of carbonyl compounds under solvent-free conditions

Carbonyl compounds are successfully converted into oxathioacetals and dithioacetals with 2-mercaptoethanol and ethane-1,2-dithiol using a catalytic amount of iron(m) fluoride under solvent-free conditions. The catalysts were recovered and reused in variou

2,4,6-Trichloro-1,3,5-triazine catalyzed chemoselective transthioacetalization of aldehyde acetals and oxathioacetals

A mild and efficient transthioacetalization of aldehyde acetals and oxathioacetals was carried out using 2,4,6-trichloro-1,3,5-triazine as a mild and inexpensive catalyst. Chemoselective transacetalization is impressive as aldehyde O,O- and O,S-acetals ar

Indium-Catalyzed Reductive Dithioacetalization of Carboxylic Acids with Dithiols: Scope, Limitations, and Application to Oxidative Desulfurization

In this study an InI3-TMDS (1,1,3,3-tetramethyldisiloxane) reducing system effectively catalyzed the reductive dithioacetalization of a variety of aromatic and aliphatic carboxylic acids with 1,2-ethanedithiol or 1,3-propanedithiol leading to the one-pot preparation of either 1,3-dithiolane derivatives or a 1,3-dithiane derivative. Also, the intact indium catalyst continuously catalyzed the subsequent oxidative desulfurization of an in situ formed 1,3-dithiolane derivative, which led to the preparation of the corresponding aldehydes.

Oxidative cross-esterification of dithiolanes with alcohols through a cross-dehydrogenative coupling (CDC)/deprotection sequence

An unprecedented oxidative cross-esterification in an equimolar mixture of dithiolanes, alcohols and water through a CDC/deprotection sequence has been developed. The reaction itself features simple experimental procedures under very mild conditions and offers a new strategic protocol for the direct and efficient synthesis of structurally diverse esters.

Silica-supported phosphorus pentoxide: A reusable catalyst for S,S-acetalization of carbonyl groups under ambient conditions

Phosphorus pentoxide supported on silica gel (P2O 5/SiO2) efficiently acts as a highly active and reusable catalyst for cyclic and non-cyclic S,S-acetalization of a variety of carbonyl compounds under mild, solvent-free an

An efficient method for chemoselective thioacetalization of aldehydes in the presence of a catalytic amount of acidic ionic liquid under solvent-free conditions

A water-stable Br?nsted acidic ionic liquid with an alkane sulfonic acid group was synthesized. This ionic liquid catalyzed the thioacetalization reaction smoothly to afford 1,3-dithianes in excellent yield and less time. In this article we describe a mil

An efficient, continuous flow technique for the chemoselective synthesis of thioacetals

By optimizing a reagent's residence time within a packed-bed reactor, it is possible to overcome selectivity issues frequently encountered in stirred reaction vessels. This important feature is demonstrated for the chemoselective protection of 4-acetylben

Perchloric acid adsorbed on silica gel (HClO4-SiO2) as an extremely efficient and reusable catalyst for 1,3-dithiolane/dithiane formation

Perchloric acid adsorbed on silica gel (HClO4-SiO2) has been found to be an extremely efficient and reusable catalyst for 1,3-dithiolane and 1,3-dithiane formation under solvent-free conditions at room temperature. Georg Thieme Verla