1064652-53-4Relevant academic research and scientific papers
"Click" methodology for synthesis of functionalized [3]catenanes: Toward higher interlocked structures
Megiatto Jr., Jackson D.,Schuster, David I.
, p. 5444 - 5448 (2009)
A study was conducted to demonstrate the use of 'click' methodology for synthesizing higher interlocked structures of functionalized [3]catenanes. The strategy was based on the separate threading of two phenanthroline string-like fragments, containing ter
Optimizing reaction conditions for synthesis of electron donor-[60]fullerene interlocked multiring systems
Megiatto Jr., Jackson D.,Spencer, Robert,Schuster, David I.
supporting information; experimental part, p. 1544 - 1550 (2011/10/05)
Reaction conditions have been developed for the preparation of a series of rotaxanes and catenanes with appended electron-donor and electron-acceptor ([60]fullerene) subunits using a straightforward one-pot procedure based on Cu(i)-template synthesis and
Introduction of useful peripheral functional groups on [2]catenanes by combining Cu(i) template synthesis with click chemistry
Megiatto Jr., Jackson D.,Schuster, David I.
experimental part, p. 276 - 286 (2010/06/14)
Two protocols based on Cu(i) template synthesis and click reactions for the synthesis of functionalized [2]catenanes are described. A straightforward procedure, involving high dilution conditions at high temperatures (70 °C), affords [2]catenanes bearing two identical peripheral groups in high yields. For the preparation of non-symmetrically functionalized [2]catenanes, a second milder and simpler protocol was developed, generalizing and extending the method. The introduction of peripheral functional groups into the catenane structure opens up possibilities of using [2]catenanes as building blocks for preparation of even more complex structures.
