106499-13-2Relevant academic research and scientific papers
A new strategy for the stereoselective syntheses of C-glycosyl compounds of β-pentapyranoses
Guo, Zhong-Wu,Hui, Yong-Zheng
, p. 2067 - 2073 (2007/10/03)
The C-glycosyl compounds of β-L-xylopyranose and β-D-arabinopyranose were conveniently prepared by reduction of methyl α-D-glucopyranoside and methyl α-D-mannopyranoside with triethylsilane in the presence of trimethylsilyl trifluoromethanesulfonate, respectively.
SYNTHESIS OF SOME DERIVATIVES OF 6-AMINO-1,5-ANHYDRO-6-DEOXY-D-GLUCITOL AND 2-AMINO-1,5-ANHYDRO-2-DEOXY-D-GLUCITOL
Witczak, Zbigniew J.,Whistler, Roy L.
, p. 121 - 132 (2007/10/02)
6-Amino-1,5-anhydro-6-deoxy-D-glucitol (11) was prepared from 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (1) in six steps.Reduction of 1 with tributyltin hydride, followed by deacetylation, monomolar tosylation, and reacetylation, afforded 2,3,4-tr
THE CHEMICAL-TRANSFORMATION PRODUCTS OF 1,6-DIBROMO-1,6-DIDEOXYGALACTITOL AND 1,2:5,6-DIANHYDROGALACTITOL IN AQUEOUS SOLUTION
Vidra, Ildiko,Simon, Kalman,Institoris, Laszlo,Csoeregh, Ingeborg,Czugler, Matyas
, p. 41 - 58 (2007/10/02)
After hydrolysis of 1,6-dibromo-1,6-dideoxygalactitol (1) and 1,2:5,6-dianhydrogalactitol (2), 11 compounds were isolated, three of them as tritylated derivatives.Their structures were established on the basis of chemical evidence and, for four compounds, by X-ray diffraction.The main product of the hydrolysis of 1 was 3,6-anhydro-1-bromo-1-deoxy-DL-galactitol; the end-products of the hydrolysis of 2 were 1,5-anhydro-DL-galactitol, 2,5-anhydro-DL-altriol and galactiotol.
