106501-83-1

Basic information

• Product Name: 2-Azetidinone, 3-(dimethylamino)-1-methyl-4-phenyl-, cis-
• CAS NO: 106501-83-1
• Molecular Formula: C12H16N2O
• Molecular Weight: 204.272
• Mol File: 106501-83-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Azetidinone, 3-(dimethylamino)-1-methyl-4-phenyl-, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Azetidinone, 3-(dimethylamino)-1-methyl-4-phenyl-, cis-(106501-83-1)
• EPA Substance Registry System: 2-Azetidinone, 3-(dimethylamino)-1-methyl-4-phenyl-, cis-(106501-83-1)

Safety Data

• Hazardous Substances Data: 106501-83-1(Hazardous Substances Data)

Upstream product

• 622-29-7 N-Benzylidenemethylamine 
• 112068-79-8 pentacarbonyl{(N,N-diphenylamino)methylene}chromium⁽⁰⁾ 
• 7148-06-3 N,N-dimethylglycine methyl ester 
• 33229-89-9 N,N-dimethylglycine ethyl ester 
• 3724-43-4 Vilsmeier reagent 

Relevant articles and documents

A new and efficient route to 3-amino-2-azetidinones via zinc enolates of N,N-disubstituted glycine esters

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The synthesis of β-lactams from zinc enolates of n,n-disubstituted α-aminoacid esters and imines: Substituent and solvent effects

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Synthesis of Amino-β-lactams by the Photolytic Reaction of Imines with Pentacarbonylchromium(0)

Chromium-carbene complexes containing the group were synthesized by the reaction of Vilsmeir's salts with Cr(CO)52-.These carbenes were remarkably air stable and resistant to attack by nucleophiles.Photolytic reaction of these complexes with imines, oxazines, oxazolines, imidates, thiazines, and thiazolines produced β-lactams in fair to good yield.In most cases trans stereochemistry was observed.Representative dibenzylamino-β-lacatms were debenzylated to produce β-lactams having a free NH2 group α to the lactam carbonyl group.