106515-80-4Relevant articles and documents
NOVEL OXIDATIVE CLEAVAGE OF CARBON-CARBON BOND IN HYDRAZONES BY OXYGENATION WITH COBALT SCHIFF BASE COMPLEX
Nishinaga, Akira,Yamazaki, Shigekazu,Matsuura, Teruo
, p. 2649 - 2652 (2007/10/02)
Oxygenation of aromatic ketone hydrazones with Co(salen) in methanol resulted unexpectedly in oxidative degradation to give methyl benzoate derivatives.A mechanism involving nucleophilic attack by methanol on a diazo intermediate is discussed.