106537-34-2

Basic information

• Product Name: Diphosphirane, 1,2-bis[2,4,6-tris(1,1-dimethylethyl)phenyl]-
• CAS NO: 106537-34-2
• Molecular Formula: C37H60P2
• Molecular Weight: 566.831
• Mol File: 106537-34-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Diphosphirane, 1,2-bis[2,4,6-tris(1,1-dimethylethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Diphosphirane, 1,2-bis[2,4,6-tris(1,1-dimethylethyl)phenyl]-(106537-34-2)
• EPA Substance Registry System: Diphosphirane, 1,2-bis[2,4,6-tris(1,1-dimethylethyl)phenyl]-(106537-34-2)

Safety Data

• Hazardous Substances Data: 106537-34-2(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 83466-54-0 Bis(2,4,6-tri-tert-butylphenyl)diphosphen 
• 186581-53-3 diazomethane 
• 93554-03-1 CH₂(P(Cl)((C₆H₂)(C(CH₃)3)3))2 

Relevant articles and documents

Exploration of isomeric bis(phosphanyl)-substituted carbenium ions: Identification and synthesis of the most stable isomer

Isomeric bis(phosphanyl) carbenium ions have been investigated by theoretical [MP2/6-31G(d,p) level of theory] and experimental means. On the potential energy surface (PES) of phosphorus cations of the formula [P 2CH5]+, f

Strong P=P π bonds: The first synthesis of a stable phosphanyl phosphenium ion

A 35-fold excess of methyl triflate (2) is required to quantitively prepare 3, the first phosphanyl phosphenium ion, from diphosphene 1. Experimental data and calculations indicate that the P=P bond becomes stronger upon alkylation.

Reductive Dehalogenation of (Cl,Br)RP-CH2-PR(Cl,Br) with Fe2(CO)9 - Formation of Complexes with Strained Diphosphirane Skeletons and Bifunctional Phosphido Bridges (μ2-PR)2CH2

P-Halogen Functional Methylenebisphosphines, Oxidative Addition, Reductive Dehalogenation, Phosphido Complexes, Diastereoselective Complexation Reductive dehalogenation of the bifunctional methylene bridged halogenphosphines XRP-CH2-PRX (X = Cl, Br; R = i