106552-88-9Relevant academic research and scientific papers
Selenoaldehydes Formed by 1,2-Elimination and Trapped as Diels-Alder Adducts
Kirby, Gordon W.,Trethewey, Andrew N.
, p. 1152 - 1154 (1986)
Various selenenyl derivatives, RO2C*CH2SeX, underwent elimination with triethylamine to form selenoaldehydes, RO2C*CHSe, which were trapped in situ as cycloadducts with conjugated dienes; the adduct of ethyl selenoxoacetate and anthracene dissociated upon heating thereby allowing transfer of the selenoaldehyde to 2,3-dimethylbuta-1,3-diene.,
The Reaction of Wittig Reagents with Selenium. Formation of Selenoaldehydes
Okuma, Kentaro,Komiya, Yasuo,Kaneko, Isao,Tachibana, Yuji,Iwata, Eiji,Ohta, Hiroshi
, p. 1653 - 1657 (2007/10/02)
The reaction of Wittig reagents with elemental selenium gave the corresponding selenoaldehydes which further reacted with other Wittig reagents to give the corresponding dimeric olefins in good yields.The selenoaldehydes formed afforded corresponding adducts by the reaction with dienes.These selenoaldehydes obtained by retro Diels-Alder reaction were also found to react with Wittig reagents to give the corresponding olefins in good yields.
GENERATION AND DIENOPHILIC REACTIVITY OF α-OXOSELENOALDEHYDES AND KETONES
Nakayama, Juzo,Akimoto, Keiichi,Niijima, Jun,Hoshino, Masamatsu
, p. 4423 - 4426 (2007/10/02)
The reaction elemental selenium with sulfur ylides stabilized by electron-withdrawing substituent(s) affords a facile method for generation of functionalized selenocarbonyl compounds, which can be effectively trapped by Diels-Alder reaction with 1,3-dienes.
