106560-86-5Relevant academic research and scientific papers
Switchable β-alkylation of secondary alcohols with primary alcohols by a well-defined cobalt catalyst
Ding, Keying,Pandey, Bedraj,Xu, Shi
, p. 1207 - 1212 (2021)
β-alkylation of secondary alcohols with primary alcohols to selectively generate alcohols by a well-defined Co catalyst is presented. Remarkably, a low catalyst loading of 0.7 mol % can be employed for the reaction. More significantly, this study represents the first Co-catalyzed switchable alcohol/ketone synthesis by simply manipulating the reaction parameters. In addition, the transformation is environmentally friendly, with water as the only byproduct.
The method of manufacturing the same
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Paragraph 0061-0065, (2017/02/02)
PROBLEM TO BE SOLVED: To provide a method for producing a dimer which can obtain the dimer even in the absence of a specific transition metal such as Ir. SOLUTION: The method for producing a dimer comprises dimerizing an alcohol (1) (wherein R1and R2are each hydrogen or a monovalent hydrocarbon group) and an alcohol (2) (wherein R3and R4are each hydrogen or a monovalent hydrocarbon group) or a carbonyl compound (3) (wherein R3and R4are the same as defined above) in the presence of an alkali metal or an alkali metal base and in the absence of a transition metal. COPYRIGHT: (C)2011,JPOandINPIT
CuI/H2/NaOH-catalyzed cross-coupling of two different alcohols for carbon-carbon bond formation: "Borrowing hydrogen"?
Miura, Takashi,Kose, Osamu,Li, Feng,Kai, Sun,Saito, Susumu
supporting information; experimental part, p. 11146 - 11151 (2011/11/14)
Not borrowed: A new method was developed for the cross-coupling of two different alcohols (see scheme). This carbon-carbon bond formation was realized by using a small amount of CuBr (0.05-0.2 mol %) and NaOH (4-20 mol %) in the presence of H2 (1 atm), and provides an alternative procedure for longer-chain alcohols. The catalytic cycle was different from those reported to date for the Guerbet reaction involving "borrowing hydrogen". Copyright
Synthesis of new (R)-secondary carbinols with different structures via enzymatic resolution
Yildiz, Tuelay,Yusufolu, Aye
experimental part, p. 1347 - 1352 (2011/11/29)
The present study deals with the biocatalytic enantioselective synthesis of 19 new chiral alcohols with alkyl (C11-C19) and phenyl, substituted phenyl, heteroaromatic, and naphthyl groups 4a-4z with an (R)-configuration and high enan
