106563-79-5Relevant academic research and scientific papers
Regioselective Nucleophilic Additions to (η6-Benzyl alcohol)tricarbonylchromium: Isolation and X-Ray Crystal Structure of the Intermediate (η6-5-Methylene-6-exo-t-butylcyclohexa-1,3-diene)tricarbonylchromium
Blagg, Julian,Davies, Stephen G.,Goodfellow, Craig L.,Sutton, Kevin H.
, p. 1283 - 1285 (1986)
Treatment of (η6-benzyl alcohol)tricarbonylchromium with alkyl-lithium compounds (t-BuLi; MeLi-tetramethylethylenediamine; n-BuLi; PhLi) regioselectively generates the corresponding η6-5-methylene-6-exo-alkylcyclohexa-1,3-diene compl
Palladium catalysed cross-coupling of (fluoroarene)tricarbonyl-chromium(o) complexes
Wilhelm, Rene,Widdowson, David A.
, p. 3808 - 3813 (2007/10/03)
(Fluoroarene)tricarbonylchromium(o) complexes were found to undergo Suzuki and Stille cross-coupling reactions to form functionalised biaryl and styrene complexes in up to 87 and 52% yields, respectively. The Suzuki reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium carbonate in DME at reflux. The Stille reactions were optimal with dipalladium tris(dibenzylideneacetone)-trimethylphosphine-caesium fluoride in DME at reflux and neither was adversely affected by a methoxy group on the complexed ring. The Suzuki reaction tolerated a chloro group on the arylboronic acid ring but not a bromo group. The Royal Society of Chemistry 2000.
Palladium catalysed cross-coupling of (fluoroarene)tricarbonylchromium(0) complexes
Widdowson, David A.,Wilhelm, Rene
, p. 2211 - 2212 (2007/10/03)
Fluoroarenetricarbonylchromium(0) complexes were found to undergo Suzuki reactions with arylboronic acids to form biaryltricarbonylchromium(0) complexes in the presence of trimethylphosphine/palladium dibenzylideneacetone and caesium carbonate or caesium
Regioselective Nucleophilic Additions to Tricarbonyl(η6-arene)chromium(0) complexes: Electronic versus Chelation Control
Blagg, Julian,Davies, Stephen G.,Goodfellow, Craig L.,Sutton, Kevin H.
, p. 1133 - 1144 (2007/10/02)
Regioselective addition of t-butyl-lithium to tricarbonyl(η6-benzyl alcohol)chromium(0) proceeds to give tricarbonyl(η6-5-methylene-6-exo-t-butylcyclohexa-1,3-diene)chromium(0), which can be isomerised to tricarbonyl(η6-o-
