106623-23-8

Basic information

• Product Name: 3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione
• Synonyms: 3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione;3,10-DihydroxydielMentha-5,11-diene-4,9-dione;(1S,4S,4aS,5R,8aR,9R)-4,4a,5,8a-Tetrahydro-5,9-dihydroxy-5,9-dimethyl-2,8-bis(1-methylethyl)-1,4-ethanonaphthalene-6,10(4H)-dione
• CAS NO: 106623-23-8
• Molecular Formula: C₂₀H₂₈O₄
• Molecular Weight: 332.43392
• Mol File: 106623-23-8.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 499.9±45.0 °C(Predicted)
• Appearance: /
• Density: 1.164±0.06 g/cm3(Predicted)
• PKA: 12.20±0.70(Predicted)
• CAS DataBase Reference: 3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione(106623-23-8)
• EPA Substance Registry System: 3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione(106623-23-8)

Safety Data

• Hazardous Substances Data: 106623-23-8(Hazardous Substances Data)

Usage

General Description

3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione is a chemical compound that is primarily known as a derivative of diterpenoids. Diterpenoids are a type of natural product that are composed of four isoprene units and have the molecular formula C20H32. They are typically found in essential oils and resin. While there isn't much specific information available on this specific compound, diterpenoid derivatives are often noted for their wide range of biological activities including anti-microbial, anti-inflammatory, anti-viral, and anti-cancer properties. The biochemical properties of 3,10-Dihydroxy-5,11-dielMenthadiene-4,9-dione may vary based on its structural and chemical features.

Upstream product

• 499-75-2 carvacrol 
• 89-83-8 thymol 
• 107535-10-4 6-acetoxy-3-isopropyl-6-methylcyclohexa-2,4-dienone 

Relevant articles and documents

Asymmetric syntheses and applications of planar chiral hypervalent iodine(V) reagents with crown ether backbones

Novel optically active hypervalent iodine(V) reagents with planar chiral crown ether backbones were synthesized using the intramolecular Huisgen reaction as a key step and L-methyl lactate as the source of chirality. The relative configurations of these r

Asymmetric hydroxylative phenol dearomatization promoted by chiral binaphthylic and biphenylic iodanes

The long-standing quest for chiral hypervalent organoiodine compounds (i.e., iodanes) as metal-free reagents for asymmetric synthesis continues. Although remarkable progress has recently been made in organoiodine-catalyzed reactions using a terminal oxidant in stoichiometric amounts, there is still a significant need for "flaskable" chiral iodane reagents. Herein, we describe the synthesis of new iodobinaphthyls and iodobiphenyls, their successful and selective DMDO-mediated oxidation into either λ3- or λ5-iodanes, and the evaluation of their capacity to promote asymmetric hydroxylative phenol dearomatization (HPD) reactions. Most notably, a C2-symmetrical biphenylic λ5-iodane promoted the HPD-induced conversion of the monoterpene thymol into the corresponding ortho-quinol-based [4+2] cyclodimer (i.e., bis(thymol)) with enantiomeric excesses of up to 94 %.

Regio- and stereoselectivities in Diels-Alder cyclodimerizations of orthoquinonoid cyclohexa-2,4-dienones

The [4+2] cyclodimerization of cyclohexa-2,4-dienone derivatives of the orthoquinone monoketal and orthoquinol types has been the topic of numerous investigations over the last 50 years in the aim of rationalizing the extraordinary level of regio-, site-,