106651-32-5

Basic information

• Product Name: (R)-N-(1-cyclohexylethyl)-P,P-diphenylphosphinamide
• Synonyms: (R)-N-(1-cyclohexylethyl)-P,P-diphenylphosphinamide
• CAS NO: 106651-32-5
• Molecular Weight: 327.406
• Mol File: 106651-32-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-N-(1-cyclohexylethyl)-P,P-diphenylphosphinamide(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-(1-cyclohexylethyl)-P,P-diphenylphosphinamide(106651-32-5)
• EPA Substance Registry System: (R)-N-(1-cyclohexylethyl)-P,P-diphenylphosphinamide(106651-32-5)

Safety Data

• Hazardous Substances Data: 106651-32-5(Hazardous Substances Data)

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 52316-19-5 cyclohexyl methyl ketone oxime 
• 106651-23-4 1-cyclohexyl-N-(diphenylphosphinyl)ethanimine 

Relevant articles and documents

Enantioselective reduction of ketones and imines catalyzed by (CN-Box)ReV-oxo complexes

The development and application of chiral, non-racemic ReV-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.

Asymmetric Reduction of Phosphinyl Imines with Hydride Reagents. Enantioselective Synthesis of Chiral Primary Amines

Prochiral diphenylphosphinyl imines are asymmetrically reduced by chiral hydride reagents to chiral diphenylphosphinylamines.For dialkyl examples, the enantioselectivities obtained are the highest thus far for hydride reductions of imine derivatives.