1066775-16-3Relevant academic research and scientific papers
Investigations into the effectiveness of deuterium as a protecting group for C-H bonds in radical reactions involving hydrogen atom transfer
Wood, Mark E.,Bissiriou, Sabine,Lowe, Christopher,Windeatt, Kim M.
, p. 3048 - 3051 (2008)
Competition experiments have been carried out to determine the extent to which deuterium can be used as a protecting group for carbon-hydrogen bonds in radical-based intramolecular hydrogen atom transfer processes.
Synthetic use of the primary kinetic isotope effect in hydrogen atom transfer: Generation of α-aminoalkyl radicals
Wood, Mark E.,Bissiriou, Sabine,Lowe, Christopher,Norrish, Andrew M.,Senechal, Katell,Windeatt, Kim M.,Coles, Simon J.,Hursthouse, Michael B.
experimental part, p. 4653 - 4665 (2010/11/17)
The extent to which deuterium can act as a protecting group to prevent unwanted 1,5-hydrogen atom transfer to aryl and vinyl radical intermediates was examined in the context of the generation of α-aminoalkyl radicals in a pyrrolidine ring. Intra- and int
