106686-63-9

Basic information

• Product Name: [(1Z)-2,3-dimethoxyprop-1-en-1-yl]benzene
• Synonyms: [(1Z)-2,3-Dimethoxyprop-1-en-1-yl]benzene; benzene, [(1Z)-2,3-dimethoxy-1-propen-1-yl]-
• CAS NO: 106686-63-9
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.2277
• Mol File: 106686-63-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 274.4°C at 760 mmHg
• Flash Point: 106.6°C
• Density: 1.012g/cm³
• Vapor Pressure: 0.00907mmHg at 25°C
• Refractive Index: 1.534
• CAS DataBase Reference: [(1Z)-2,3-dimethoxyprop-1-en-1-yl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(1Z)-2,3-dimethoxyprop-1-en-1-yl]benzene(106686-63-9)
• EPA Substance Registry System: [(1Z)-2,3-dimethoxyprop-1-en-1-yl]benzene(106686-63-9)

Safety Data

• Hazardous Substances Data: 106686-63-9(Hazardous Substances Data)

Upstream product

• 77-78-1 dimethyl sulfate 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 86-51-1 2,3-dimethyoxybenzaldehyde 
• 148-53-8 3-methoxy-2-hydroxybenzaldehyde 
• 19754-21-3 1-allyl-2,3-dimethoxy-benzene 
• 65492-28-6 o-benzoquinone bis(dimethyl acetal) 
• 29283-76-9 propenyl lithium 
• 76049-02-0 1-(2,3-dimethoxyphenyl)-1-propanol 

Downstream Products

• 1076-55-7 (E/Z)-2-(1-Propenyl)-6-methoxyphenol 

Relevant articles and documents

Crossing the Boundaries between Marine and Muguet: Discovery of Unusual Lily-of-the-Valley Odorants Devoid of Aldehyde Functions

Since 6-isopropyl- (11) and 6-isobutyl-2H-benzo[b][1,4]dioxepin-3(4H)-one (12) instead of the expected marine odor had been reported to possess lily-of-the-valley notes, albeit weaker than benchmark odorants, the influence of a cyclopropyl ring instead of

Synthesis of [2-(methoxyaryl)-1-methylethyl]phosphinic acids from red phosphorus and (allyl)(methoxy)benzenes

(Allyl)(methoxy)benzenes react with red phosphorus in the superbasic system KOH-DMSO in the presence of small amounts of water and hydroquinone (3 h, 130 C) to regio- and chemoselectively give [2-(methoxyaryl)-1-methylethyl]phosphinic acids in preparative yields up to 52%. The reactions involve isomerization of allylbenzenes into (prop-1-enyl)benzenes.

REACTION OF o-BENZOQUINONE BISACETALS WITH ORGANOLITHIUMS. A NOVEL ROUTE TO SUBSTITUTED VERATROLES

Substituted veratroles were easily obtained by the reaction of o-benzquinone bisacetals with organolithiums.