106709-73-3

Upstream product

• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 928-95-0 (E)-2-Hexen-1-ol 

Downstream Products

• 90633-60-6 1-[((E)-Hex-2-ene)-1-sulfonyl]-4-methyl-benzene 
• 89268-72-4 (R)-1-(hex-1-en-3-ylsulfonyl)-4-methylbenzene 
• 89268-71-3 (S)-(+)-1-hexen-3-yl p-tolyl sulfone 
• 105235-55-0 (E)-1-(hex-2-en-1-ylsulfonyl)-4-methylbenzene 
• 111727-05-0 (+/-)-1-hexen-3-yl-p-tolyl sulfone 
• 1208401-72-2 C₁₃H₁₈O₂S 
• 74810-84-7 dimethyl 2-hexenylmalonate 
• 92747-24-5 (+)-2-(1-propyl-allyl)-malonic acid dimethyl ester 
• 92747-23-4 dimethyl (S)-(+)-1-hexen-3-ylmalonate 

Relevant academic research and scientific papers

Tandem Ir-catalyzed allylic substitution reaction of allyl sulfinates and isomerization

(Chemical Equation Presented) An efficient method for the synthesis of trisubstituted vinyl sulfones is reported. Using the [lr(COD)Cl] 2/phosphoramidite ligand (L1)/DBU, trisubstituted vinyl sulfones could be synthesized from allyl sulfinates

Palladium-Catalyzed Allylic Sulfinate-Sulfone Rearrangements

Upon treatment with a zero-valent palladium catalyst, tetrakis(triphenylphosphine)palladium, in tetrahydrofuran under mild conditions allylic p-toluenesulfinates underwent α- or γ-rearrangements of the sulfonyl group via ionic intermediates to give allylic sulfones.The regiochemistry of the rearrangements depends on the character of the intermediary allylic cationic carbons generated and the steric hindrance involved therein.Keywords - allylic sulfinate; allylic sulfone; palladium catalyst; sulfinate-sulfone rearrangement; regiochemistry; tetrakis(triphenylphosphine)palladium.