1067175-36-3 Usage
Uses
CHLORONORBORNADIENETRIPHENYLPHOSPHINERHODIUM (I) is versatile polymer-bound catalyst used for the selective hydrogenation of polyolefins. The supported rhodium catalyst exhibits similar selectivity to its homogeneous counterpart. In most cases, rhodium leaching is negligible.
Reactions
Suzuki-Miyaura Coupling of Aryl Chlorides (low catalyst loading).
Check Digit Verification of cas no
The CAS Registry Mumber 1067175-36-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,6,7,1,7 and 5 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1067175-36:
(9*1)+(8*0)+(7*6)+(6*7)+(5*1)+(4*7)+(3*5)+(2*3)+(1*6)=153
153 % 10 = 3
So 1067175-36-3 is a valid CAS Registry Number.
1067175-36-3Relevant articles and documents
A new family of tunable indolylphosphine ligands by one-pot assembly and their applications in Suzuki-Miyaura coupling of aryl chlorides
Chau, Ming So,Chung, Chiu Yeung,Chak, Po Lau,Fuk, Yee Kwong
, p. 7803 - 7806 (2008/12/22)
(Chemical Equation Presented) This study describes a new class of indolylphosphine ligands, which can be easily accessed by a simple one-pot assembly from commercially available indoles, acid chlorides, and chlorophosphines. A combination of these three starting materials provides a high diversification of the ligand structure. The application of this ligand array in palladium-catalyzed Suzuki-Miyaura coupling reaction of aryl chlorides with arylboronic acids is described. A catalyst loading down to 0.01 mol % of Pd can be achieved.
