106729-33-3Relevant academic research and scientific papers
PREPARATION OF α-METHYLENE KETONES BY THE PALLADIUM-CATALYZED DECARBOXYLATION-DEACETOXYLATION OF ALLYL α-ACETOXYMETHYL-β-KETO CARBOXYLATES UNDER MILD CONDITIONS
Tsuji, Jiro,Nisar, Mohammad,Minami, Ichiro
, p. 2483 - 2486 (1986)
α-Methylene ketones are prepared in high yields by the palladium-catalyzed decarboxylation-deacetoxylation of allyl α-acetoxymethyl-β-keto carboxylates.The reaction proceeds rapidly at room temperature under neutral conditions in acetonitrile.
Synthesis and olfactory properties of spirocyclic Georgywood analogues
Kraft, Philip,Frech, David,Mueller, Urs,Frater, Georg
, p. 2215 - 2223 (2006)
Spirocyclic analogues of Georgywood (3) and unlike-10-acetyl-9,10- dimethylbicyclo[6.4.0]dodec-1(8)-ene (4), in which the acetyl moiety and the methyl substituent of C-10 are part of a cyclopentyl or cyclohexyl ring, were synthesized from 8a-homomyrcene (
