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Asymmetric Reduction of Chiral Acetophenone Oxime Ethers to Optically Active Primary Amines
Itsuno, Shinichi,Tanaka, Kazuo,Ito, Koichi
, p. 1133 - 1136 (2007/10/02)
Chiral oxime ethers were synthesized from Na salt of acetophenone oxime and chiral halides, tosylates, or N-tosylaziridines which were derived from β-pinene or α-amino acids.Asymmetric reduction of the chiral oxime ether with LiAlH4 or BH3*THF gave the optically active primary amine.
