1067670-05-6

Basic information

• Product Name: bis(phenylphosphine)(phthalocyaninato)iron(II)
• CAS NO: 1067670-05-6
• Molecular Weight: 788.57
• Mol File: 1067670-05-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(phenylphosphine)(phthalocyaninato)iron(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(phenylphosphine)(phthalocyaninato)iron(II)(1067670-05-6)
• EPA Substance Registry System: bis(phenylphosphine)(phthalocyaninato)iron(II)(1067670-05-6)

Safety Data

• Hazardous Substances Data: 1067670-05-6(Hazardous Substances Data)

Upstream product

• 132-16-1 iron(II) phthalocyanine 
• 638-21-1 phenylphosphane 

Relevant articles and documents

Primary and secondary phosphine complexes of iron porphyrins and ruthenium phthalocyanine: Synthesis, structure, and P-H bond functionalization

Reduction of [FeIII(Por)Cl] (Por = porphyrinato dianion) with Na2S2O4 followed by reaction with excess PH2Ph, PH2Ad, or PHPh2 afforded [Fe II(F20-TPP)(PH2Ph)2] (1a), [Fe II(F20-TPP)(PH2Ad)2] (1b), [Fe II(F20-TPP)(PHPh2)2] (2a), and [FeII(2,6-Cl2TPP)(PHPh2)2] (2b). Reaction of [RuII(Pc)(DMSO)2] (Pc = phthatocyaninato dianion) with PH2Ph or PHPh2 gave [RuII(Pc) (PH2Ph)2] (3a) and [RuII(Pc)(PHPh 2)2] (4). [RuII(Pc)(PH2Ad) 2] (3b) and [RuII(Pc)(PH2But) 2] (3c) were isolated by treating a mixture of [Ru II(Pc)(DMSO)2] and O=PCl2Ad or PCl 2But with LiAlH4. Hydrophosphination of CH 2=CHR (R = CO2Et, CN) with [RuII(F 20-TPP)(PH2Ph)2] or [RuII(F 20-TPP)(PHPh2)2] in the presence of tBuOK led to the isolation of [RuII(F20-TPP) (P(CH2CH2R)2Ph)2] (R = CO 2Et, 5a; CN, 5b) and [RuII(F20-TPP)(P(CH 2CH2R)Ph2)2] (R = CO2Et, 6a; CN, 6b). Similar reaction of 3a with CH2=CHCN or Mel gave [RuII(Pc)(P(CH2CH2CN)2Ph) 2] (7) or [RuII(Pc)(PMe2Ph)2] (8). The reactions of 4 with CH2=CHR (R = CO2Et, CN, C(O)Me, P(O)(OEt)2, S(O)2Ph), CH2=C(Me)CO 2Me, CH(CO2Me)=CHCO2Me, Mel, BnCl, and RBr (R = nBu, CH2=CHCH2, MeC≡CCH2, HC≡CCH2) in the presence of tBuOK afforded [Ru II(Pc)(P(CH2CH2R)Ph2)2] (R = CO2Et, 9a; CN, 9b; C(O)Me, 9c; P(O)(OEt)2, 9d; S(O)2Ph, 9e), [RuII(Pc)(P(CH2CH(Me)CO 2Me)Ph2)2] (9f), [RUII(PC) (P(CH(CO2Me)CH2CO2Me)Ph2) 2] (9g), and [RuII(Pc)(PRPh2)2] (R = Me, 10a; Bun, 10b; Bn, 10c; CH2CH=CH2, 10d; CH2C≡CMe, 10e; CH=C=CH2, 10f). X-ray crystal structure determinations revealed Fe-P distances of 2.2597(9) (1a) and 2.309(2) A(2b·2CH2Cl2) and Ru-P distances of 2.3707(13) (3b), 2.373(2) (3c), 2.3478(11) (4), and 2.3754(10) A(5b·2CH2Cl2). Both the crystal structures of 3b and 4 feature intermolecular C-H ... π interactions, which link the molecules into 3D and 2D networks, respectively.