106776-02-7Relevant academic research and scientific papers
NUCLEOPHILIC THIONATION OF POLYFLUORINATED β-DICARBONYL COMPOUNDS
Pashkevich, K. I.,Saloutin, V. I.,Bobrov, M. B.,Yufit, D. S.,Struchkov, Yu. T.
, p. 2162 - 2166 (2007/10/02)
The reaction of polyfluorinated β-diketones with tetraphosphorus decasulfide and potassium carbonate in acetonitrile is accompanied by the condensation to Z-4-methyl-6-perfluoroalkyl-2-(perfluorothioacylmethylene)-2H-thiopyrans.The structures of these compounds were demonstrated by x-ray crystallography.In this reaction polyfluorinated β-ketoesters give the corresponding 1,2-dithiolene-3-thiones.
