1067915-47-2Relevant academic research and scientific papers
The influence of oligo(ethylene glycol) side chains on the self-assembly of benzene-1,3,5-tricarboxamides in the solid state and in solution
Stals, Patrick J. M.,Haveman, Jan F.,Martin-Rapun, Rafael,Fitie, Carel F. C.,Palmans, Anja R. A.,Meijer
experimental part, p. 124 - 130 (2009/04/10)
Substituted benzene-1,3,5-tricarboxamides (BTAs) 1-4 comprising polar tetraethyleneglycol (tetraEG) and/or apolar (R)-3,7-dimethyloctyl side chains were synthesised and their self-assembly in the solid state and in solution was investigated. While BTA 1 (
The influence of ethylene glycol chains on the thermodynamics of hydrogen-bonded supramolecular assemblies in apolar solvents
De Greef, Tom F. A.,Nieuwenhuizen, Marko M. L.,Stals, Patrick J. M.,Fitie, Carel F. C.,Palmans, Anja R. A.,Sijbesma, Rint P.,Meijer
supporting information; experimental part, p. 4306 - 4308 (2009/03/12)
Substitution of hydrogen bond directed supramolecular assemblies with ethylene glycol chains leads to a reduction in the association constant in apolar solvents, where the reduction of the association constant is dependent on the length of the aliphatic spacer connecting the hydrogen bonds and the ethylene glycol chain. The Royal Society of Chemistry.
