106800-22-0Relevant academic research and scientific papers
Robustadials. 2. Total Synthesis of the Bicycloheptane Structure Proposed for Robustadials A and B
Lal, Kasturi,Zarate, Eugene A.,Youngs, Wiley J.,Salomon, Robert G.
, p. 3673 - 3680 (2007/10/02)
Total synthesis of the bicycloheptane structure 2a proposed for robustadial A was achieved.The molecular architecture of the synthetic product was unambiguously established by X-ray crystallographic analysis of an intermediate in the synthesis.Howe
Hydroxyl-Directed Regioselective Monodemethylation of Polymethoxyarenes
Lal, Kasturi,Ghosh, Subrata,Salomon, Robert G.
, p. 1072 - 1078 (2007/10/02)
Methoxyl groups ortho to β-hydroxyethyl or γ-hydroxypropyl substituents in polymethoxybenzene derivatives were regioselectively demethylated with sodium thioethoxide in N,N-dimethylformamide.Methoxydihydrobenzofurans or methoxychromans were produced by cyclization of the monodemethylated β-hydroxyethyl or γ-hydroxypropyl derivatives, respectively.
