106800-24-2Relevant academic research and scientific papers
Preparation of olefins from alcohols by thermal rearrangement of propargylic xanthates
Faure-Tromeur, Melanie,Zard, Samir Z.
, p. 1305 - 1308 (2007/10/03)
Upon heating in toluene in the presence of a catalytic amount of collidinium trifluorosulfonate salt, various S-propargylic xanthates derived from secondary alcohols can be easily converted to their corresponding olefins in good yields.
Hydroxyl-Directed Regioselective Monodemethylation of Polymethoxyarenes
Lal, Kasturi,Ghosh, Subrata,Salomon, Robert G.
, p. 1072 - 1078 (2007/10/02)
Methoxyl groups ortho to β-hydroxyethyl or γ-hydroxypropyl substituents in polymethoxybenzene derivatives were regioselectively demethylated with sodium thioethoxide in N,N-dimethylformamide.Methoxydihydrobenzofurans or methoxychromans were produced by cyclization of the monodemethylated β-hydroxyethyl or γ-hydroxypropyl derivatives, respectively.
