1068459-75-5Relevant academic research and scientific papers
A facile one-pot synthesis of α-halo,α-allylic aldehydes from α,α-dihalo ketones utilizing allylic zinc bromide
Wang, Xiaolei,Zhang, Songlin
, p. 96 - 102 (2012/03/10)
An efficient synthesis of various α-halo,α-allylic aldehydes from α,α-dihalo ketones using both cyclic (3-bromocyclohex-1-ene zinc bromide and (Z)-3-bromocyclobut-1-ene zinc bromide) and acyclic (allylzinc bromide and cinnamylzinc bromide) type of allylic organozinc bromide with DMF as base is described. A possible reaction mechanism is also proposed. Copyright
A facile synthesis of two series of multifunctional carbon compounds from α,α-dihalo ketones using allylsamarium bromide
Liu, Xiaodan,Zhang, Songlin,Di, Jucai
experimental part, p. 2749 - 2755 (2010/01/21)
The use of allylsamarium bromide to effect two different reactions on the common starting material, a,a-dihalo ketones, is presented. With DMF, α-halo-α-allyl aldehydes were obtained, while α-hydroxy- α-allyl aldehyde acetals were obtained in the presence of NaOMe/MeOH. Georg Thieme Verlag Stuttgart.
A facile one-pot synthesis of a?-halo-a?-allyl-aldehydes from a?,a?-Dihaloketoncs Using Allylsamarium Bromide and DMF
Di, Jucai,Zhang, Songlin
experimental part, p. 1491 - 1494 (2009/04/07)
A convenient, one-pot synthesis of a range of a?-halo-a?-allyl aldehydes is described. The protocol involves the reaction of allylsamarium bromide with various a?,a?-dihalo ketones. A possible mechanism of the transformation is proposed.
