1068465-05-3

Basic information

• Product Name: N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide
• Synonyms: N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide
• CAS NO: 1068465-05-3
• Molecular Weight: 253.368
• Mol File: 1068465-05-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide(1068465-05-3)
• EPA Substance Registry System: N-phenyl-N-[(E)-2-phenylvinyl]thioacetamide(1068465-05-3)

Safety Data

• Hazardous Substances Data: 1068465-05-3(Hazardous Substances Data)

Upstream product

• 637-53-6 thioacetanilide 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Ruthenium-catalyzed stereoselective anti-markovnikov-addition of thioamides to alkynes

(Chemical Equation Presented) A catalyst system generated in situ from bis(2-methallyl)-cycloocta-1,5-diene-ruthenium(ll) and a phosphine was found to efficiently catalyze the addition of thioamides to terminal alkynes with exclusive formation of the anti-Markovnikov thioenamide products. The stereoselectivity of the addition is usually high and controlled by the choice of the phosphine ligand, whereas the (E)-isomers are predominantly formed in the presence of tri(n-octyl)phosphine, the use of bis(dicyclohexylphosphino)methane preferentially leads to the formation of the (Z)-configured thioenamides.