1068655-35-5

Basic information

• Product Name: 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-germanaphthalene
• CAS NO: 1068655-35-5
• Molecular Weight: 877.043
• Mol File: 1068655-35-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-germanaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-germanaphthalene(1068655-35-5)
• EPA Substance Registry System: 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-2-bromo-3-tert-butyl-1,2-dihydro-2-germanaphthalene(1068655-35-5)

Safety Data

• Hazardous Substances Data: 1068655-35-5(Hazardous Substances Data)

Upstream product

• 135139-64-9 2,4,6-tris(bis(trimethylsilyl)methyl)phenylgermanium trichloride 
• 1068655-38-8 C₆H₂(CH(Si(CH₃)3)2)3GeBr₃ 
• 211508-96-2 3-tert-butyl-1H-isotellurochromene 
• 128-08-5 N-Bromosuccinimide 
• 1068655-39-9 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-3-tert-butyl-1,2-dihydro-2-germanaphthalene 

Downstream Products

• 1068655-39-9 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-3-tert-butyl-1,2-dihydro-2-germanaphthalene 
• 1068655-33-3 2-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-3-tert-butyl-2-germanaphthalene 

Relevant articles and documents

Synthesis and properties of stable 2-metallanaphthalenes of heavier group 14 elements

The first stable neutral stannaaromatic compound, 2-stannanaphthalene 1a, was synthesized by taking advantage of an extremely bulky and efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt). The molecular structure and aromaticity of 1a were discussed on the basis of X-ray crystallographic analysis, NMR, UV-vis, and Raman spectroscopy, cyclic voltammetry, and theoretical calculations. 2-Germanaphthalene 2a, which has a framework similar to that of 1a, was synthesized for comparison, and systematic elucidation was made for the properties of 2-metallanaphthalene systems containing a heavier group 14 element (Si, Ge, or Sn).