106888-17-9Relevant academic research and scientific papers
SYNTHESIS OF 3-(ALKYLARYL)-1-ADAMANTANOLS
Kovalev, V. V.,Knyazeva, I. V.,Shokova, E. A.
, p. 692 - 696 (2007/10/02)
The possibility was demonstrated for removal of hydride ions from 1-(alkylaryl)adamantanes by tertiary carbocations generated from the corresponding alcohols or halides in trifluoroacetic acid leading to the formation of 3-(alkylaryl)-1-adamantanols in 40-60percent yield.In the case of 1-phenyladamantane, the major product is 1-(1-adamantyl)-4-benzene formed in 71percent yield due to presence of two reaction sites (the benzene ring para position and the tertiary carbon atom of the adamantane fragment) in the starting 1-phenyladamantane.
