106889-50-3Relevant academic research and scientific papers
Vinyl Azides in Heterocyclic Synthesis. Part 2. Selectivity in the Decomposition of Azidocinnamates with Olefinic ortho-Substituents
Hickey, Deirdre M. B.,Moody, Christopher J.,Rees, Charles W.
, p. 1113 - 1118 (2007/10/02)
Thermolysis of azidocinnamates with an olefinic o-substituent gives products (isoquinolines, azepines, aziridines) formed by selective interaction of the azide, and the derived nitrene, with the olefinic substituent, cyclisation onto the unsubstituted aro
Selectivity in Vinyl Azide Reactions; Decomposition of Azidocinnamates with Olefinic ortho-Substituents
Hickey, Deirdre M. B.,Moody, Christopher J.,Rees, Charles W.
, p. 1419 - 1421 (2007/10/02)
Thermal decomposition of vinyl azides (1a - c) gives isoquinolines (3), benzazepines (4), or aziridines (5) and (6) by preferential reaction at the unsaturated substituent; removal of this unsaturation as in the epoxides (1d, 1e) leads exclusively to 4-substituted indoles.
