1069116-82-0

Upstream product

• 246864-29-9 (E)-5,9-andhydro-6,7,8,10-tetra-O-benzyl-1,2-N,O-isopropylidene-2-(tert-butoxycarbonylamino)-2,3,4-trideoxy-D-erythro-L-talo-dec-3-enitol 
• 102308-32-7 (4S)-4-formyl-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester 
• 108149-63-9 4-hydroxymethyl-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester 
• 246864-27-7 (S)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(thiomethyl)-1,3-oxazolidine 
• 441044-67-3 (4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(thiomethyl)-1,3-oxazolidine 
• 246864-28-8 (4S)-S-(2',6'-anhydro-3',4',5',7'-tetra-O-benzyl-1'-deoxy-D-glycero-D-gulo-heptitol-1'-yl)-N-(tert-butoxycarbonyl)-2,2-dimethyl-4-(sulfonylmethyl)-1,3-oxazolidine 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 246864-34-6 methyl 5,9-andhydro-6,7,8,10-tetra-O-benzyl-2-(tert-butoxycarbonylamino)-2,3,4-trideoxy-D-erythro-L-talo-deconate 

Relevant academic research and scientific papers

General synthesis of C-glycosyl amino acids via proline-catalyzed direct electrophilic α-amination of C-glycosylalkyl aldehydes

(Chemical Equation Presented) Non-natural axially and equatorially linked C-glycosyl α-amino acids (glycines, alanines, and CH2-serine isosteres) with either S or R α-configuration were prepared by D- and L-proline-catalyzed (de >95%) α-aminati

exo-Glycal approaches to C-linked glycosyl amino acid synthesis

Two novel routes to C-linked glycosyl amino acids are described; the first involves elaboration of an exo-glycal and subsequent Ramberg-Backlund rearrangement of a sulfone intermediate to give, after functional group manipulation, a protected C-glycosyl serine, while the second uses hydroboration-Suzuki coupling of the same exo-glycal to produce ultimately the corresponding C-glycosyl asparagine analogue.