106924-49-6Relevant academic research and scientific papers
REACTION DU TRIMETHYL CHLOROSILANE AVEC LES ALCOOLS α-CYCLOPROPANIQUES EN PRESENCE OU EN L'ABSENCE D'HALOGENURES DE LITHIUM.
Balme, Genevieve,Fournet, Guy,Gore, Jacques
, p. 1907 - 1908 (1986)
α-Cyclopropyl alcohols react with Me3SiCl, eventually in the presence of LiBr or LiI, leading to a cyclopropyl halide or (and) to a homopropargylic halide, according to the nature of the alcohol.
Homologation Reaction of γ-Silicon Substituted Allylic Alcohols Using Organoaluminium Reagents and Diiodomethane
Ukaji, Yutaka,Inomata, Katsuhiko
, p. 2353 - 2356 (1992)
One carbon homologation reaction of γ-silicon substituted allylic alcohols was found to proceed by the treatment with triethylaluminium followed by diethylaluminium chloride and diiodomethane to afford homoallylic iodides instead of the corresponding cyclopropanes.Silicon function introduced to γ-position was crucial for the homologation reaction.
SUBSTITUTED CYCLOPENTANES HAVING PROSTAGLANDIN ACTIVITY
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Page/Page column 8, (2009/05/28)
Disclosed herein are compounds having a formula: Therapeutic methods, medicaments, and compositions related thereto are also disclosed.
