107022-88-8Relevant articles and documents
Improved Synthesis of Racemate and Enantiomers of Taniguchi Lactone and Conversion of Their C-C Double Bonds into Triple Bonds
Malová Kri?ková, Petra,Lindner, Wolfgang,Hammerschmidt, Friedrich
, p. 651 - 657 (2017/11/15)
cis -2-Butene-1,4-diol was heated with triethyl orthoacetate and p -hydroquinone as catalyst at 170 °C to give racemic Taniguchi lactone. It was converted into diastereomeric amides with (S)-1-phenylethylamine for stereoisomer resolution. The double bonds
Facile production scale synthesis of (S)-Taniguchi lactone: A precious building-block
Von Kieseritzky, Fredrik,Wang, Yeliu,Axelson, Magnus
, p. 643 - 645 (2014/06/09)
A cost-efficient and facile synthesis of (S)-4-vinyldihydrofuran-2(3H)-one ((S)-1), better known as (S)-Taniguchi lactone, is described. Racemic Taniguchi lactone rac-1 was ring-opened with (S)-1-benzylmethylamine providing a diastereomeric mixture of hyd
Synthesis and Absolute Configuration of the Acetalic Lignan(+)-Phrymarolin I
Ishibashi, Fumito,Taniguchi, Eiji
, p. 4361 - 4366 (2007/10/02)
The natural (+)-phrymarolin I was stereoselectively synthesized and its absolute configuration was unequivocally determined as being (1S,2S,5R,6S)-1-acetoxy-2-(2-methoxy-4,5-methylenedioxyphenoxy)-6-(2-methoxy-4,5-methylenedioxyphenyl)-3,7-dioxabicyclooctane.
Synthesis and Absolute Configuration of (+)-Phrymarolin I, a Lignan
Ishibashi, Fumito,Taniguchi, Eiji
, p. 1771 - 1774 (2007/10/02)
(+)-Phrymarolin I was synthesized from (S)-(+)-β-vinyl-γ-butyrolactone, and the absolute configuration of the natural product was established as (1S,2S,5R,6R).