107047-80-3Relevant academic research and scientific papers
Preparation of rearranged allylic isocyanates from the reaction of allylic alcohols with 1-Cyano-4-dimethylaminopyridinium bromide
Baidilov, Daler,Makarova, Mariia,Rycek, Lukas,Hudlicky, Tomas
, p. 4606 - 4610 (2018)
A shorter and less costly alternative to Ichikawa's [1,3]-Transposition protocol for cyanates to isocyanates is described.
A new synthetic method for the preparation of amino sugars through an allyl cyanate-to-isocyanate rearrangement
Ichikawa, Yoshiyasu,Osada, Masafumi,Ohtani, Ikuko I.,Isobe, Minoru
, p. 1449 - 1455 (2007/10/03)
A new approach for the synthesis of amino sugars using an allyl cyanate-to-isocyanate rearrangement has been developed. The key feature in this method involves introduction of the nitrogen substituent into the pyranose framework by [3,3] sigmatropic rearrangement of an allyl cyanate. Subsequent functionalization of the allylamine moiety by either hydroxylation or cyclofunctionalization completes the synthesis of two amino sugars, D-perosamine and D-vicenisamine.
