1070743-76-8Relevant articles and documents
Selenirenium and tellurirenium ions
Poleschner, Helmut,Seppelt, Konrad
supporting information; experimental part, p. 6461 - 6464 (2009/03/11)
Canted chalcogens: Relatively stable selenirenium salts (R1 2C2SeR)+X- (R1=tert- alkyl) are prepared by reaction of RSe+X- with acetylenes; the bond angle at selenium is only 38°. Highly unstable tellurirenium salts (R12C2TePh)+X- from PhTe+X- and di-tert-alkylacetylenes have a bond angle at tellurium of 34° (see picture). These three-membered-ring cations were experimentally and theoretically investigated. (Chemical Equation Presented).