107108-79-2

Upstream product

• 107108-77-0 {(Z)-2-[(2R,3S,6R)-6-Allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-yl]-1-phenylsulfanyl-vinyl}-trimethyl-silane 
• 110-87-2 3,4-dihydro-2H-pyran 
• 82740-87-2 (2R,3S,6R)-2-acetoxymethyl-6-allyl-3,6-dihydro-2H-pyran-3-yl acetate 
• 95791-07-4 (2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol 
• 107108-76-9 (2S,3S,6R)-6-Allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-carbaldehyde 
• 107108-74-7 Acetic acid (2R,3S,6R)-6-allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-ylmethyl ester 
• 2873-29-2 D-glucal triacetate 
• 107108-75-8 [(2R,3S,6R)-6-Allyl-3-(tetrahydro-pyran-2-yloxy)-3,6-dihydro-2H-pyran-2-yl]-methanol 
• 107108-73-6 Acetic acid (2R,3S,6R)-6-allyl-3-hydroxy-3,6-dihydro-2H-pyran-2-ylmethyl ester 

Downstream Products

• 107108-82-7 (2R,3S,6R)-6-Allyl-2-((Z)-2-benzenesulfonyl-2-trimethylsilanyl-vinyl)-3,6-dihydro-2H-pyran-3-ol 
• 107108-81-6 (2R,3S,6R)-6-Allyl-2-((E)-2-benzenesulfonyl-2-trimethylsilanyl-vinyl)-3,6-dihydro-2H-pyran-3-ol 
• 107108-96-3 (2R,3S,6R)-6-Allyl-2-((S)-2-benzenesulfonyl-1-methyl-ethyl)-3,6-dihydro-2H-pyran-3-ol 
• 107108-97-4 (2R,3S,6R)-6-Allyl-2-((R)-2-benzenesulfonyl-1-methyl-ethyl)-3,6-dihydro-2H-pyran-3-ol 

Relevant academic research and scientific papers

ACYCLIC STEREOCONTROL BY HETEROCONJUGATE ADDITION--4 ANTI-DIASTEREOSELECTION BY A β-CHELATION EFFECT

High selectivity in heteroconjugate addition for C-C bond formation with complete syn-diastereoselection has been attributed to the chelation effect between the α-oxygen atom of the substrate and the nucleophile anions through metal cations.Herein is desc