107116-07-4Relevant academic research and scientific papers
N-CYCLOALKYL-N-[(TRISUBSTITUTEDSILYLPHENYL)METHYLENE]-(THIO)CARBOXAMIDE DERIVATIVES
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Page/Page column 52, (2013/11/05)
The present invention relates to fungicidal N-cycloalkyl-N-[(trisubstitutedsilylphenyl)methylene] carboxamide derivatives and their thiocarbonyl derivatives, their process of preparation and intermediate compounds for their preparation, their use as fungicides, particularly in the form of fungicidal compositions and methods for the control of phytopathogenic fungi of plants using these compounds or their compositions.
Et-duphos-nickel-catalyzed asymmetric arylation of benzaldehyde derivatives bearing an ortho-Me2PhSi group with potassium aryltriolborates
Sakurai, Fumie,Kondo, Kazuhiro,Aoyama, Toyohiko
experimental part, p. 6001 - 6003 (2010/03/01)
The Ni-catalyzed asymmetric arylation of benzaldehydes bearing an ortho-masked H group with potassium aryltriolborates has been developed. The keys to success were (i) steric tuning of benzaldehyde derivatives with an ortho-Me2PhSi group, and (
1,3-Bis(2-benzoylphenyl)-1,1,3,3-tetramethyldisiloxane
Wiese, Dietmar,Wannagat Ulrich,Thewalt, Ulf,Debaerdemaeker, Tony
, p. 873 - 878 (2007/10/02)
Attempts to prepare 9,9-dimethyl-9-sila-10(9H)-anthracenone (4a) from dimethylphenyl-2-tolylsilane (5) or 2-bromobenzoic acid as starting compounds via 2-(dimethylphenylsilyl)benzoyl chloride (11a) by condensation with tin tetrachloride resulted in high yields of the title compound 14a.Determination of its structure was only possible by X-ray analysis, determination of the course of the reaction by variation with 2-benzoyl chloride (11b) and mass spectroscopical investigation of the resulting isomeric mixture of bistetramethyldisiloxanes 14b,b',b''.
