107127-66-2Relevant articles and documents
Synthesis of α-diketones from alkylaryl- and diarylalkynes using mercuric salts
Jung, Michael E.,Deng, Gang
supporting information, p. 2142 - 2145 (2014/05/06)
Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do not provide the diketone product. A possible mechanism is proposed.
Heterocycle-heterocycle strategies: (2-nitrophenyl)isoxazole precursors to 4-aminoquinolines, 1 H-indoles, and quinolin-4(1 H)-ones
Coffman, Keith C.,Palazzo, Teresa A.,Hartley, Timothy P.,Fettinger, James C.,Tantillo, Dean J.,Kurth, Mark J.
supporting information, p. 2062 - 2065 (2013/06/05)
Reductive heterocycle-heterocycle (heterocycle → heterocycle; H-H) transformations that give 4-aminoquinolines, 3-acylindoles, and quinolin-4(1H)-ones from 2-nitrophenyl substituted isoxazoles are reported. When this methodology is applied to 3,5-, 4,5-,
Photoreactions of 1,2-bis-(2-nitrophenyl)ethane
Rajasekharan, K. N.,Sulekha, A.
, p. 697 - 699 (2007/10/03)
The photolysis of 1,2-bis(2-nitrophenyl)ethane 1 is predominated by intermolecular redox process of the nitro group to afford 2-nitrobenzoic acid 4, 2-nitrobenzyl 2'-nitrophenyl ketone 5, 2,2'-dinitrobenzil 6 and dibenzo[c,g][1,2]diazocin-5,6-dione-N,N'-dioxide 7. In contrast, the lower homologue bis (2-nitrophenyl)methane is reported to undergo mainly intramolecular photoprocesses.
Enamines: Part III - A New Synthesis of Substituted 2-Arylisatogens and o-Nitrophenyl Benzyl Ketones
Bhamare, N. K.,Kamath, H. V.,Kulkarni, Sheshgiri N.
, p. 613 - 615 (2007/10/02)
Condensation of substituted o-nitrobenzoyl chloride with o/p-nitro substituted β-morpholinostyrenes gives α-acyl-β-morpholinostyrenes which are converted into the title compounds.
