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Enamines et enediamines: synthese et oxydation anodique. Application a la formation de nouveaux heterocycles
Cariou, Michel,Carlier, Roger,Simonet, Jacques
, p. 781 - 792 (2007/10/02)
The anodic oxidation of certain tertiary enamines and enediamines is particularly sensitive to the medium effect: specific action of bases leading to either dimers or trimers, or to the formation of a new 3 H-indole (case of enamines); reaction with moisture in the solvent allowing the obtention of indolooxazolidines (case of enediamines).The reactivity of the oxidized forms of the substrates is discussed as a function of the nature of the electrolysis medium and the structure of the products amenable to electrolysis.
