107174-23-2Relevant academic research and scientific papers
Reduction of Cyclic Hemiacetals. The Synthesis of Demethoxyeleutherin and Nanaomycin A
Kraus, George A.,Molina, Maria Teresa,Walling, John A.
, p. 1568 - 1569 (1986)
The reduction of cyclic hemiacetals containing two stereogenic centres is highly stereoselective.
Synthesis of Deoxyfrenolicin and Nanaomycin A
Kraus, George A.,Molina, Maria Teresa,Walling, John A.
, p. 1273 - 1276 (2007/10/02)
Deoxyfrenolicin and nanaomycin A have been synthesized.Key steps in the synthesis include a phtalide annulation reaction to produce a naphthoquinone, a tandem Diels-Alder/retro-Claisen reaction to produce the carbon skeleton, and a stereoselective reduction of a hemiketal.
