107175-12-2Relevant academic research and scientific papers
Stereochemistry in the Reactions of (Z)- and (E)-Allyltributylstannyl Reagents with Quinones
Takuwa, Akio,Soga, Osamu,Mishima, Taeko
, p. 1261 - 1265 (2007/10/02)
In the BF3-catalyzed allylation of quinones with allylstannyl reagents, (Z)-hexenyltributylstannane (3) is introduced with no retention of the original double-bond stereochemistry, and neryl reagent (5) is introduced with partial loss of olefin stereochemistry.In contrast, (E)-2-hexenyltributylstannane (4) and geranyltributylstannane (6) are introduced with complete retention of their olefin geometries.
