107183-35-7

Upstream product

• 7766-51-0 4-iodobut-1-ene 
• 7706-83-4 (E)-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester 

Downstream Products

• 107183-36-8 2-(1-3'-methoxyphenylethenyl)-5-hexen-1-ol 
• 120402-14-4 N-<2-(1-3'-methoxyphenylethenyl)-5-hexenyl>-4-phenylthiooxazolidin-2-one 
• 120402-18-8 5,5a,6,7,8,8a,9,9a-octahydro-8a-(3-methoxyphenyl)-8-methyl-1H,3H-oxazolo<3,4-a>cyclopentapyridin-3-one 
• 120402-08-6 4-Hydroxy-3-{2-[1-(3-methoxy-phenyl)-vinyl]-hex-5-enyl}-oxazolidin-2-one 
• 107183-47-1 (2S,4aS,7R,8S,12bS)-8-Hydroxy-2,11-dimethoxy-1,2,3,4,4a,5,7,8-octahydro-7,12b-methano-dibenzo[c,e]azocine-6-carboxylic acid benzyl ester 
• 107183-47-1 (2S,4aS,7R,12bS)-8-Hydroxy-2,11-dimethoxy-1,2,3,4,4a,5,7,8-octahydro-7,12b-methano-dibenzo[c,e]azocine-6-carboxylic acid benzyl ester 
• 107183-40-4 (3S,4aR,6R,8aR)-3-Formyl-6-methoxy-4a-(3-methoxy-phenyl)-octahydro-isoquinoline-2-carboxylic acid benzyl ester 
• 107183-40-4 (3R,4aR,6R,8aR)-3-Formyl-6-methoxy-4a-(3-methoxy-phenyl)-octahydro-isoquinoline-2-carboxylic acid benzyl ester 
• 107206-00-8 N-<2-(1-3'-methoxyphenylethenyl)-5-hexenyl>oxazolidine-2,4-dione 
• 107183-39-1 (3R,4aR,6R,8aR)-3-Hydroxymethyl-6-methoxy-4a-(3-methoxy-phenyl)-octahydro-isoquinoline-2-carboxylic acid benzyl ester 
• 107183-41-5 (4aS,6S,8aS)-6-Methoxy-4a-(3-methoxy-phenyl)-octahydro-isoquinoline-2-carboxylic acid benzyl ester 
• 107183-44-8 (4aS,6S,8aS)-6-Formyloxy-4a-(3-methoxy-phenyl)-octahydro-isoquinoline-2-carboxylic acid methyl ester 
• 107183-37-9 Formic acid (5aR,8R,9aR,10aR)-9a-(3-methoxy-phenyl)-3-oxo-decahydro-oxazolo[3,4-b]isoquinolin-8-yl ester 
• 107183-42-6 2-{2-[1-(3-Methoxy-phenyl)-vinyl]-hex-5-enyl}-isoindole-1,3-dione 

Relevant academic research and scientific papers

EFFECT OF A-STRAIN. DIASTEREOSELECTIVE SYNTHESIS OF 3,2'-METHYLENE BRIDGED CIS-4a-ARYLDECAHYDROISOQUINOLINE RING SYSTEM VIA N-ACYLIMINIUM ION-POLYENE RING CLOSURE

Diastereoselective synthesis of 3,2'-methylene bridged 6-oxygenated 4a,6-cis-4a,8a-cis-4a-aryldecahydroisoquinoline ring system was achieved by an application of N-acyliminium ion-polyene cyclization at the initial stage.

A Highly Diastereoselective Synthesis of cis-4a-Aryloctahydro-cyclopentapyridine Derivatives through Tandem Radical Cyclization of α-amino Radical Polyene Species

8a-Aryloxazolocyclopentapyridines (9a-c) were prepared via a route involving radical cyclization of α-acylamino radical polyene species generated by treatment of 4-phenylthiooxazolidin-2-ones (8a-c) with tri-n-butyltin hydride in the presence of azobisisobutyronitrile (AIBN).Conversion of 9a to cis-octahydro-2,5-dimethyl-4a-phenylcyclopentapyridine (19) was successfully achieved via a route involving ring cleavage of the oxazolidinone ring of 9a, oxidation of hydroxymethyl group, and decarbonylation.Keywords - radical cyclization; cyclopentapyridine; α-acylamino radical; α-amino radical-polyene; tandem radical cyclization; decarbonylation