107196-50-9Relevant academic research and scientific papers
Stereoselective Reactions. XI. Asymmetric Alkylation of Cyclohexanone via Chiral Chelated Lithioenamines Derived from D-Camphor Derivatives
Ikota, Nobuo,Sakai, Hiroshi,Shibata, Hisanari,Koga, Kenji
, p. 1050 - 1055 (2007/10/02)
Metalation and alkylation of the chiral imines prepared from cyclohexanone and methoxy amines (2b, 4c, 6d and 7d) derived from D-camphor derivatives provided, after hydrolysis, optically active 2-alkylcyclohexanones (9) in high enantiomeric purities of up to 99.5percent.Keywords - asymmetric synthesis; asymmetric alkylation; D-camphor; chiral methoxy amine; 2-alkylcyclohexanone; chelated lithioenamine.
