107196-54-3

Upstream product

• 501-53-1 benzyl chloroformate 
• 107196-53-2 (1S,2R)-1-(hydroxymethyl)-2-amino-7,7-dimethyl-bicyclo<2.2.1>heptane 
• 74-88-4 methyl iodide 
• 107298-00-0 ((1S,2R,4R)-1-Hydroxymethyl-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl)-carbamic acid benzyl ester 
• 107196-53-2 ((1S,4R)-2-Amino-7,7-dimethyl-bicyclo[2.2.1]hept-1-yl)-methanol 
• 107196-51-0 (1S,4R)-1-hydroxymethyl-7,7-dimethylbicyclo[2.2.1]heptan-2-one oxime 

Downstream Products

• 107196-57-6 Cyclohexylidene-((1S,2R,4R)-1-methoxymethyl-7,7-dimethyl-bicyclo[2.2.1]hept-2-yl)-amine 

Relevant academic research and scientific papers

Stereoselective Reactions. XI. Asymmetric Alkylation of Cyclohexanone via Chiral Chelated Lithioenamines Derived from D-Camphor Derivatives

Metalation and alkylation of the chiral imines prepared from cyclohexanone and methoxy amines (2b, 4c, 6d and 7d) derived from D-camphor derivatives provided, after hydrolysis, optically active 2-alkylcyclohexanones (9) in high enantiomeric purities of up to 99.5percent.Keywords - asymmetric synthesis; asymmetric alkylation; D-camphor; chiral methoxy amine; 2-alkylcyclohexanone; chelated lithioenamine.