107205-97-0Relevant academic research and scientific papers
Nickel-Catalysed Allylboration of Aldehydes
Dennis, Francesca M.,Partridge, Benjamin M.,Robertson, Craig C.
, p. 1903 - 1914 (2020)
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.
REDUCTIVE GENERATION OF ACTIVE ZERO-VALENT TIN IN SnCl2-Al SYSTEM AND ITS USE FOR HIGHLY DIASTEREOSELECTIVE REACTION OF CINNAMYL CHLORIDE AND ALDEHYDES.
Uneyama, Kenji,Nanbu, Hiromi,Torii, Sigeru
, p. 2395 - 2396 (2007/10/02)
Highly diastereoselective reaction of cinnamyl chloride with aldehydes was achieved by the use of active zero-valent tin generated in SnCl2-Al system.
