107265-38-3Relevant articles and documents
On the parity in helical twisting power of Ru(III) 1,3-diketonates of C2 symmetry in nematic liquid crystals
Yoshida, Jun,Sato, Hisako,Yamagishi, Akihiko,Hoshino, Naomi
, p. 8453 - 8456 (2007/10/03)
It is demonstrated that the sign of helical twisting power (HTP) of an enantiomeric Ru(III) complex of type [Ru(acac)2L] can be switched by choosing L from either Lper or Lpara, which is elongated either perpendicular or p
SYNTHESIS OF LIQUID CRYSTALLINE 3,5-DIARYL 1,2-DITHIOLIUM SALTS
Veber, M.,Jallabert, C.,Strzeleska, H.
, p. 693 - 702 (2007/10/02)
The title compounds are obtained by heterocyclisation of dialkoxy substituted diaryl β-diketones or chalcones using P4S10.
Discotic Liquid Crystals of Transition Metal Complexes, 3: the First-Established Discotic Lamellar Phase in Biscopper(II)
Ohta, Kazuchika,Muroki, Hiromitsu,Takagi, Akira,Hatada, Koh-Ichi,Ema, Hiroshi,et al.
, p. 131 - 152 (2007/10/02)
A new series of disk-like complexes, biscopper(II) (abbreviated as CnO-Cu, n = 1-12), has been synthesized.It was found that each of the complexes from C3O-Cu to C12O-Cu is a discogen, and that each of them has only one discotic mesophase.C3O-Cu is the first compound substituted by the shortest side chains in the discogen, so far as we know.The mesomorphic textures could be observed as mosaic textures for C3O-Cu ca.C5O-Cu and a big broken fan-like textures for C6O-Cu ca.C12O-Cu.The eutectic point calculated from Le Chatelier-Schroeder relations agrees well with the found eutectic point in the binary phase diagram between C8O-Cu and C8-Cu.This is the first example of such agreement in the discogens of the organic transition metal complexes.It has been established for the first time from X-ray diffraction measurements that each of the discotic mesophases in the complexes from C6O-Cu to C12O-Cu is a discotic lamellar phase.It becomes clear that this discotic mesophase is truly a new discotic lamellar phase (DL) different from the mesophase in C10-Cu, and that the DL phase has a structure in which the molecules tilt to the layers.Keywords: discotic liquid crystal, transition metal complex, bis(β-diketonato)copper(II), discotic lamellar phase