1072798-30-1

Basic information

• Product Name: C₁₄H₁₈O₃S₂
• Synonyms: C₁₄H₁₈O₃S₂
• CAS NO: 1072798-30-1
• Molecular Weight: 298.427
• Mol File: 1072798-30-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₈O₃S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₈O₃S₂(1072798-30-1)
• EPA Substance Registry System: C₁₄H₁₈O₃S₂(1072798-30-1)

Safety Data

• Hazardous Substances Data: 1072798-30-1(Hazardous Substances Data)

Upstream product

• 22068-49-1 4-(1,3-dithiolan-2-yl)phenol 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 22068-49-1 4-(1,3-dithiolan-2-yl)phenol 

Relevant articles and documents

Organocatalytic methods for chemoselective O-tert-butoxycarbonylation of phenols and their regeneration from the O-t-Boc derivatives

(Chemical Equation Presented) Carbon tetrabromide (CBr4) catalyzes O-tert-butoxycarbonylation of functionalized phenols without any side reactions (bromination, addition of CBr3 to a double bond, and formation of symmetrical diaryl carbonates, cyclic carbonates, or carbonic-carbonic anhydrides). The parent phenols are regenerated from the O-t-Boc derivatives by the catalyst system CBr4-PPh3 without affecting other protecting groups (aryl alkyl ether, alkyl ester, and thioacetal) or competitive side reaction such as bromination, nitrene (from NO2) and α,α-dibromoolefine (with CHO/COMe) formation, and transesterification (with CO2Me/Et) taking place.