1072800-64-6

Basic information

• Product Name: 1-(naphth-1-yl)-2-phenyl-2,2-bis(propylthio)ethanol
• CAS NO: 1072800-64-6
• Molecular Weight: 396.618
• Mol File: 1072800-64-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(naphth-1-yl)-2-phenyl-2,2-bis(propylthio)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(naphth-1-yl)-2-phenyl-2,2-bis(propylthio)ethanol(1072800-64-6)
• EPA Substance Registry System: 1-(naphth-1-yl)-2-phenyl-2,2-bis(propylthio)ethanol(1072800-64-6)

Safety Data

• Hazardous Substances Data: 1072800-64-6(Hazardous Substances Data)

Upstream product

• 60595-12-2 Benzaldehyd-dipropylmercaptal 
• 66-77-3 1-naphthaldehyde 

Downstream Products

• 1072800-65-7 1-(2-phenyl-1,2-bis(propylthio)vinyl)naphthalene 

Relevant articles and documents

Elimination of β-thioalkoxy alcohols under Mitsunobu conditions. A new synthesis of conjugated enynes from propargylic dithioacetals

(Chemical Equation Presented) Treatment of propargylic dithiolanes 1 with nBuLi followed by a carbonyl electrophile yields the corresponding homopropargylic alcohol 3. Upon treatment with 2 equiv of PPh3 and DIAD, elimination of SR and OH moieties from 3 affords the corresponding olefins 4 in moderate to good yield. The reaction can be considered an alternative of McMurry coupling of two different carbonyl equivalents.