1072849-24-1Relevant articles and documents
Pushing the limits of steric demand around a biaryl axis: Synthesis of tetra-ortho-substituted biaryl naphthalenes
Glass, Adam C.,Klonoski, Sam,Zakharov, Lev N.,Liu, Shih-Yuan
, p. 286 - 288 (2011/03/18)
The synthesis of tetra-ortho-substituted biaryl naphthalenes, including examples bearing multiple ortho-isopropyl groups, has been developed via a catalytic rearrangement process.
Synthesis of substituted naphthalenes via a catalytic ring-expansion rearrangement
Glass, Adam C.,Morris, Benjamin B.,Zakharov, Lev N.,Liu, Shih-Yuan
supporting information; experimental part, p. 4855 - 4857 (2009/05/31)
(Figure Presented) A new methodology for the preparation of substituted naphthalenes starting from readily available indenones, organometal reagents, and trimethylsilyldiazomethane via a catalytic rearrangement process is described. Hindered biaryl naphthalenes, including triortho-substituted biaryls, can be accessed through our method. Our results are consistent with a mechanism involving a benzobenzvalene intermediate.
