1072901-09-7

Basic information

• Product Name: Pincer ligand
• Synonyms: Pincer ligand;N2-[2-(Dimethylamino)phenyl]-N1,N1-dimethyl-1,2-benzenediamine;Bis[(2-diMethylaMino)phenyl]aMine
• CAS NO: 1072901-09-7
• Molecular Formula: C₁₆H₂₁N₃
• Molecular Weight: 255.35804
• Product Categories: Achiral Nitrogen;Py-N
• Mol File: 1072901-09-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 356.5±27.0 °C(Predicted)
• Appearance: /
• Density: 1.103±0.06 g/cm3(Predicted)
• PKA: 7.17±0.50(Predicted)
• CAS DataBase Reference: Pincer ligand(CAS DataBase Reference)
• NIST Chemistry Reference: Pincer ligand(1072901-09-7)
• EPA Substance Registry System: Pincer ligand(1072901-09-7)

Safety Data

• Hazardous Substances Data: 1072901-09-7(Hazardous Substances Data)

Upstream product

• 1033772-51-8 [(MeNN₂)NiPh] 
• 123726-16-9 bis(4-methylphenyl)iodonium trifluoromethanesulfonate 
• 698-00-0 2-bromo-N,N-dimethylaniline 
• 1242273-80-8 ((Me)N₂N)Ni-H 
• 615-36-1 2-bromoaniline 
• 1493-27-2 ortho-nitrofluorobenzene 
• 2836-03-5 N,N-dimethyl-1,2-phenylenediamine 

Downstream Products

• 1033772-51-8 [(MeNN₂)NiPh] 
• 644-08-6 4-Methylbiphenyl 
• 1033772-47-2 [((Me)NN₂)NiCl] 
• 1361927-06-1 [(N(C₆H₄N(CH₃)2)2)2Ni] 

Relevant articles and documents

Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes

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Syntheses of transition metal methoxysiloxides

The paper describes three methods for the preparation of methoxysiloxide complexes, a rare class of complexes of relevance to room temperature vulcanization (RTV) of polysiloxanes. The salt metathesis reaction involves the use of the recently described re

Pd, Pt, and Ru complexes of a pincer bis(amino)amide ligand

An improved synthesis of pincer ligand bis[(2-dimethylamino)phenyl]amine (MeN2NH) was reported. Reaction of the Li complex of MeN2N with suitable Pd, Pt, and Ru precursors gave the corresponding metal complexes. The structures of the Pd, Pt, and Ru complexes were determined. The Ru complex showed activity in catalytic transfer hydrogenation of aryl and alkyl ketones. The Royal Society of Chemistry 2011.