107298-10-2Relevant academic research and scientific papers
Synthetic and Theoretical Studies of Cyclobuta[1,2:3,4]dicyclopentene. Organocobalt Intermediates in the Construction of the Unsaturated Carbon Skeleton and Their Transformation into Novel Cobaltacyclic Complexes by C-C Insertion
Myers, Andrew G.,Sogi, Miki,Lewis, Michael A.,Arvedson, Stephen P.
, p. 2516 - 2525 (2007/10/03)
Theoretical and synthetic studies of the tricyclic 10π-electron hydrocarbon cyclobuta[1,2:3,4]-dicyclopentene (1), a nominally aromatic structure that has never been synthesized, are described. Geometry optimization by density-functional-theory calculatio
Stereoselective formation of cyclic bisallenes from 5,5,10,10-tetrabromotricyclo[7.1.0.0.4,6] decanes
Dehmlow, Eckehard V.,Stiehm, Thomas
, p. 1841 - 1844 (2007/10/02)
The stereochemical outcome of the title conversions is predicted and tested. Within detection limits, the transformations of the stereoisomeric compounds1,2,3, and5 to the cyclic bisallenes 9 and 10 occur stereospecifically.1 -3 all yieldmeso compound9;5 givesrac-10. Isomer4 is not yet available for analogous experiments. (Chemical Equation Presented).
